Electronic properties of francium diatomic compounds and prospects for cold molecule formation

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Electronic properties of Francium diatomic compounds and prospects for cold molecule formation

In this work we investigate the possibility to create cold Fr2, RbFr, and CsFr molecules through photoassociation of cold atoms. Potential curves, permanent and transition dipole moments for the Francium dimer and for the RbFr and RbCs molecules are determined for the first time. The Francium atom is modelled as a one valence electron moving in the field of the Fr core, which is described by a ...

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electronic spectral line shape of a diatomic molecule

the electronic absorption spectral line shape of a diatomic molecule with harmonic potential curves is calculated using the time correlation function formalism. both the equilibrium shift and the frequency shift of the two linking electronic states ate taken into account. the spectrum is also calculated using the cumulated expansion which is related to the correlation function of the time-depen...

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ژورنال

عنوان ژورنال: Journal of Physics B: Atomic, Molecular and Optical Physics

سال: 2006

ISSN: 0953-4075,1361-6455

DOI: 10.1088/0953-4075/39/19/s07